Anthony J. Morrison was arrested about 11:30 Saturday after the incident at 11 Brooklawn Court.
Police said Morrison had been involved in an altercation with a family member, and after it ended, he fired a shot toward the victim and her husband.
Morrison was charged with aggravated domestic assault and reckless endangerment.
He was jailed in the Washington County Detention Center on $30,000 bond. A Sessions Court appearance was set for Monday.